为了提高基于聚氧化乙烯(PEO)的聚合物电解质的室温电导率,以PEO为聚合物主体、LiClO4或LiN(CF3SO2)2为盐、SiO2为填充剂,以溶液浇铸法制备了它的复合聚合物电解质.电导率测试表明,PEO15LiN(CF3SO2)2-10%SiO2在30℃的电导率为4.67×10-5S/cm.
作 者： 路密 史鹏飞 尹鸽平  
作者单位： 哈尔滨工业大学应用化学系,黑龙江,哈尔滨,150001 
刊 名： 电池  ISTIC PKU
英文刊名： BATTERY BIMONTHLY 
年，卷(期)： 2002 32(z1) 
分类号： TM912.9 
关键词： 锂离子电池   聚合物电解质   复合聚合物电解质   电导率  
机标分类号： O63 TM9 
机标关键词： 复合聚合物电解质室温电导率聚氧化乙烯溶液浇铸填充剂法制测试 
基金项目：  
DOI：  

参考文献(11条)
CROCE F.Appetecchi G B.Persi L Nanocomposite polymer electrolytes for lithium batteries 1998
CROCE F.Persi L.Ronci F Nanocomposite polymer electrolytes and their impact on the lithium battery technology 2000
CROCE F.Persi L.Scrosati B Role of the ceramic fillers in enhancing the transport properties of composite polymer electrolytes 2001
Riberiro R.Silva G G.Mohallem N D S A comparison of ionic con ductivity,thermal behavior and morphology in two polyether-LilLiAl5O8 composite polymer electrolytes 2001
SUN H Y.Sohn H J.Yamamoto O Enhanced lithium-ion transport in PEO-based with composite polymer electrolytes with ferroelec tric BaTiO3 1999(5)
SUN H Y.Takeda Y.Imanishi N Ferroelectric materials as a ce ramic filler in solid composite polyethylene oxide-based electrolytes 2000(7)
Chen H W.Chang F C The novel polymer electrolyte nanocomposite composed of poly (ethylene oxide), lithium triflate and mineral clay 2001
Capiglia C.Mustarelli P.Quartarone E Effects of nanoscale SiO2 on the thermal and transport properties of solvent-free, poly( ethylene oxide) ( PEO )-based polymer electrolytes 1999
CROCE F.Persi L.Scrosati B Role of the ceramic fillers in en hancing the transport properties of composite polymer electrolytes 2001
Wieczorek W.Siekierski M A description of the temperature depen dence of the conductivity for composite polymeric electrolytes by effective medium theory 1994
Scrosati B.Croce F.Panero S Progress in lithium polymer battery R&D 2001

引证文献(2条) 
杨金鑫.孙方民.尹艳红.岳红云.杨伟光.杨书廷 新型复合聚合物电解质膜的制备及性能 [期刊论文] -电池2006(02)
马俊涛.梁美霞.李洪武.吴少娇.张翠芬 PEO基纳米复合聚合物电解质 [期刊论文] -电池2004(05)

原文链接：http://d.wanfangdata.com.cn/Periodical_dc2002z1015.aspx