碱性锌空气电池具有比能量高、工作电压平稳、原材料廉价易得等优点,是实用化研究的目标.但此电池放电电流密度低,且电池性能受外界环境影响大,使其应用和发展受到了极大的限制.对近年来国内外在氧还原电催化剂、空气电极结构、空气预处理技术及锌电极结构方面的研究进展、发展前景进行了讨论.
作 者: 褚有群 马淳安 张文魁
作者单位: 浙江工业大学应用化学系,浙江,杭州,310032
刊 名: 电池 ISTIC PKU
英文刊名: BATTERY BIMONTHLY
年,卷(期): 2002 32(5)
分类号: TM911.41
关键词: 空气电极 电催化剂 锌空气电池 碱性电解液
机标分类号: TM9 O63
机标关键词: 电极结构氧还原电催化剂碱性锌空气电池预处理技术应用和发展环境影响工作电压电流密度电池性能电池放电原材料实用化比能量目标国内
基金项目:
DOI:
参考文献(46条)
宋文顺 化学电源工艺学 1998
李国欣 新型化学电源导论 1992
CHAKKARAVARTHY C.Waheed A K A.Udupa H V K Zinc-air alkaline batteries-a review 1981
Mclanrnon F R.Cairns E J The secondary alkaline zinc electrode 1991(2)
Yeager E Electrocatalysts for O2 reduction 1984
隋升.顾军.李光强 PEMFC氧电极研究动向 2000(13)
Ye S Y.Vijh A K.Dao L H Oxygen reduction on a new electrocatalyst based on highly porous carbonized polyacrylonitrile microcellular foam with very low platinum loading 1996
Choi K H.Kim H S.Lee T H Electrode fabrication for proton exchange membrane fuel cells by pulse electrodeposition 1998
Genies L.Faure R.Durand R Electrochemical reduction of oxygen on platinum nanoparticles in alkaline media 1998
Li Y J.Chang C C.Wen T C A mixture design approach to thermally prepared Ir-Pt-Au ternary electrodes for oxygen reduction in alkaline solution 1997
Jose H Z.Miguel G.Mauricio I Linear versus volcano correlations between electrocatalytic activity and redox and electronic properties of metallophthalocycanines 1998
吕鸣祥 扣式锌-空气电池的研究进展 1987(3)
Sakai T.Iwaki T.YeZ Air-metal hydride battery construction and evaluation 1995(12)
吴智远 空气电极应用研究 [期刊论文] -武汉大学学报(自然科学版)1991(3)
Borbely A.Molla J Cathode for zinc air cells 1990
Passaniti J.Dopp R B Metal-air cathode and cell having catalytically active manganese compounds of valance state 2 1994
Passaniti J.Dopp R B Method of making air cathode material having catalytically active manganese compounds of valance state 2 1995
李升宪.周贵茂.艾新平.杨汉西 圆柱型锌空气电池研究 [期刊论文] -电化学2000(3)
De Faria LA.Prestat M.Koenig J F Surface properties of Ni+Co mixed oxides:a study by X-rays,XPS,BET and PZC 1998
李能.李士杰.孟宪平 超细LiMn2-xMxO4和LiCo1-xMxO2的合成及其在碱溶液中的电催化活性研究 [会议论文] 1999
戚祖强.仇卫华 双功能氧电极LiCoMn2-xO4催化性能的研究 [会议论文] 1999
Halliop W.Kirchnerova J.Karpinski A Bifunctional electrodes for electrically rechargeable Zn/Air cells 2000
顾军.隋升.李光强 La1-xCaxFe1-yCoyO3对氧气还原的催化活性 [期刊论文] -无机材料学报1999(4)
Hyodo T.Hayashi M.Miura N Catalytic activities of rare-earth manganites for cathodic reduction of oxygen in alkaline solution 1996(11)
Hyodo T.Hayashi M.Mitsutake S Praseodymium-calcium manganites (Pr1-xCaxMnO3) as electrode catalyst for oxygen reduction in alkaline solution 1997(27)
Youichi S.Kenichi U.Haruyuki M Bi-functional oxygen electrode using large surface area La1-xCaxCoO3 for rechargeable metal-air battery 1990(11)
Trovarelli A.Zamar F.Lorca J Nanophase fluorite-structured CeO2-ZrO2 catalysts prepared by high-energy mechanical milling-analysis of low-temperature redox activity and oxygen storage capacity 1997(2)
CeO2在Pd/γ-Al2O3催化剂中的助剂作用 [期刊论文] -应用化学1999(1)
KUWAHA K.Matsuoka A Air electrode for fuel cell and manufacture thereof 1998
MORI T.Imahashi J.Kamo T Phosphoric acid absorption and performance of gas diffusion electrode
吕玲红.金丽华.王均涛 质子交换膜燃料电池的氧电极 [期刊论文] -电源技术2001(2)
邓惠莉.范祥清.常天祥 "复合"空气阴极的研究 1988(3)
Kawahara T Electrode for fuel cell and manufacture of power generation layer 1998
Kawahara T Electrode for fuel cell and power generation layer,and its manufacture 1988
李瑛.王林山 燃料电池 2000
Pedicini C S Diffusion controlled air vent for a metal-air battery 1997
Pedicini C S.Witzigrueter J D Diffusion controlled vent and recirculation air manager for a metal-air battery 1999
Pedicini C S.Witzigrueter J D Air-managing system for metal-air battery using resealable septum 2001
Foller P C Improved slurry zinc/air systems as batteries for urban vehicle propulsion 1986
Evans J W.Savaskan G A zinc-air cell employing a packed bed anode 1996
SAVASKAN G.Huh T.Evans J W Further studies of a zinc-air cell employing. a packed bed anode(Ⅰ) Discharge 1992(22)
HUH T.Savaskan G.Evans J W Further studies of a zinc-air cell employing a packed bed anode(Ⅱ) Regeneration of zinc particles and electrolyte by fluided bed electrodeposition 1992(22)
SALAS-MORALES J C.Evans J W Further studies of a zinc-air cell employing a packed bed anode(Ⅲ) Improvements in cell design 1994(24)
Siu S.Evans J W Flow and transport due to natural convection in a galvanic cell(Ⅰ) Development and a mathematical model 1997(8)
Siu S.Evans J W Flow and transport due to natural convection in a galvanic cell(Ⅱ) Experimental measurements of velocity and cell potentials and comparison with the mathematical model 1997(8)
Goldstein J.Brown I.Koretz B New Developments in the Electric Fuel Ltd. Zinc/air System 1999
引证文献(17条)
李文雅.王明召 一则高中化学课外阅读材料——锌空气电池 [期刊论文] -中国教育技术装备2009(9)
司玉军.熊中平.陈昌国.李敏娇.封雪松 十二烷基苯磺酸钠对AZ31镁合金缓蚀作用研究 [期刊论文] -稀有金属材料与工程2007(12)
郭瑞敏.杨占红.苏赵辉 氧电极催化剂La0.6Ca0.4CoO3的合成及性能 [期刊论文] -电池2007(03)
张灿.田建华.单忠强.陈延禧 氧还原催化剂LaMn1-yCryO3的制备与性能 [期刊论文] -电池2007(02)
欧秀芹.梁广川.梁秀红 烧结对空气电极的寿命及微孔结构的影响 [期刊论文] -功能材料2006(04)
冯燕.杨占红.谷鹏.张宝.桑商斌.李再峰 氧电极气体扩散层的研究 [期刊论文] -电池2006(02)
张建 电动汽车电池监控系统设计 [学位论文] 硕士2006
司玉军 镁电池电极材料的电化学行为研究 [学位论文] 硕士2006
徐献芝.朱梅.杨基明 一种敞口式锌空固定电源 [期刊论文] -节能技术2005(02)
蒋巍 空气电池锌电极的制备与研究 [学位论文] 硕士2005
