二次锂离子电池在充放电过程中,由于过充电或过放电、电解液氧化分解、钝化膜的形成、活性物质的溶解及其他现象会导致电池容量损失,综述了锂离子电池容量损失的原因并对其反应机理作简要阐述.
作 者： 黄可龙 吕正中 刘素琴  
作者单位： 中南大学化学化工学院, 
刊 名： 电池  ISTIC PKU
英文刊名： BATTERY BIMONTHLY 
年，卷(期)： 2001 31(3) 
分类号： TM912.9 
关键词： 二次锂离子电池   容量损失   电解液氧化   自放电  
机标分类号： TM9 O64 
机标关键词： 二次锂离子电池电池容量损失原因分析氧化分解活性物质放电过程反应机理过放电过充电钝化膜电解液溶解 
基金项目：  
DOI：  

参考文献(40条)
Katsuhisa T.uchi A.Fajimoto H Charge-discharge characteristics of the mesocarbon miocrobeads heat-treated at different temperatures 1995(4)
吴宇平.方世璧.江英彦 锂在炭材料中的可逆高储存机理 [期刊论文] -化学通报1998(4)
Doyle M.Newan J.Gozdz A S Comparison of modeling predictions with experimental data from plastic lithium ion cells 1996(6)
DAHN J R.Fuller E W.Obravae M Overcharge reations for high-voltage positive electrodes 1994
Breen J M.Mansour.Melendres An in situ X-ray absorption spectroscopic study ofcharged Li(1- x) Ni(1+ z) O2 cathode mathode material 1999(8)
Liu W.Kowal K.Farrington G C Mechnism of the electrochemical insertion of lithium into LiMn2O4 spinels 1998(2)
Ein-Eli Yair.Markovsky B.Aurbach D The dependence of the performance of Li-C intercalation anodes for Li-ion secondary batteries on the electrolyte solution composition 1994(17)
Li Tao.Balbuene P B Theoretical studies of lithium perchlorate in ethylene carbonate propylene carbonate and their mixtures 1999(10)
TARASCON J M.Guyomard D Li metal-free rechargcable batteries based on Li1+ x Mn2O4 cathodes ( 0≤ x ≤ 1 ) and carbon anodes 1991(10)
Fong R.Von Sacken U.Dahn J R Studies of lithium intercalation into carbons using nonaqueous electrochemical eells 1990(7)
Aubach D.Ein-Eli Yair.Chusid O The correlation between the surface chemistry and the performance of Li-carbon intercalation anodes for rechargeable" rocking-chair” type batteries 1994(3)
Ein-Eli Y.Mchdevitl S F.Aurbach D Methyl carbonate: A promiscuous single solvent for Li-ion battery electrlytes 1997(7)
Aurbach D.Markorsky B.Shechter A A comparative study of synthetic graphite and Li electrodes in electrolyte solutions based on et hylene carbonate - dimethyl carbonate mixtures 1996(12)
城上保 新电池读本 1987
Blyr A.Sigala C.Amatucci Self-discharge of LiMn2O4/C Li -ion cells in their discharged state 1998(1)
PISTOIA G.Antonini A.Rosati R Storage characteristics of cathode for Li-ion batteries 1996(17)
Zone D.toca G.Zhang Y ome aspects of LiMn2O4 electrochemistry in the 4 volt range 1995(8)
王先友.张允什.阎杰 锂离子电池碳负极研究新动向 [期刊论文] -电源技术1999(4)
ED E.Golodnitsky D.Atdel G The semi model-application to lithium-polymer electroyte batteries 1995(13)
Shu Z X.Mcmillan R S.Murrary J J Electrochemical intercalation of lithium into graphite 1993(4)
Chen Y.Devine T M.Evans J W Examination of the corrosion behavior of aluminum current collectors in lithium/polymer batheries 1999(4)
TORIYAMA S.amura K.Shiraishi S Studies on electrochemical oxidation of nonaqueous electrolytes using in still FTIR spectroscopy 1995(5)
ckeray M M Stuctural consideration of layered and spinel lithiated oxides for lithium ion batteries 1995(8)
Mckinnon W Rascon.Coowar F Synthesis conditions and oxygen stoichiometry effects on Li insertion into the spinel LiNn2O4 1994(6)
illing Oliver.Dahn J R Thermodynamic stability of chemically delithiated Li(LixMn2-x)O4 1998(2)
Ein - Eli Y.o-Horn Y.Robertson A D Morphology modification and dilithiation mechanisms of LiMn2O4 and Li2MnO3 by acid digestion 1998(1)
Robertson A D.Lu S H Howard W F M3+ - modified LiMn2O4 spinel intercalation cathodes 1997(10)
Van der Ven Anton.Aayinol M K.Ceder G First - principles evidence for stage ordering in LixCoO2 1998(6)
Tobishima S I.Hayashi K.Saito K Influence of electrolyte composition of ethylene carbonate/propylene carbonate mixed systems on the properties of rechargeable Li/amorphous V2O5 - P2O5cells 1997(1)
詹晖.周运鸿 锂离子电池正极材料的发展 [期刊论文] -电源技术1999(Z1)
Xia Yougyao.Yoshio M An investigation of lithium ion insertion into spinel structure Li- Mn- O compounds 1996(3)
Yamada A.Miura K.Hinokuma K Sythesis and structure aspects of LiMn2O4+ δ as a cathodes for rechargeable lithium batteries 1995(7)
胡晓宏 LiMn2O4正极在高温下性能衰退现象的研究 [期刊论文] -电化学1999(2)
Li Guohua.Ikuta H.Uchida T The spinel phases LiMyMn2-y O4M = Co Ct Ni)as the cathode for rechargeable lithium batteries 1996(1)
ARORA P.Popov B N.White R E Electrochemical investigations of cobalt - doped LiMn2O4 as cathode material for lithium - ion batteries 1998(3)
唐致远.薛建军.许雪莲 锂离子电池正极材料的研究 1999(4)
Kato J.Ohzuku T.Sacoai K Electrochemistry of manganese dioxide in lithium nonaqueous cells-IV Jahn-Teller deformation of MnO6 octahedron in LixMnO2 1991(9)
Ohzuku T.Ueda A.Nagayma M Electrochemistry and structural chemistry of LiNiO2 (Rsm) for 4 - volt secondary lithium cells 1993(7)
THACKERAY M M.Gummov R J Characterization of LT - Lix CO1-y NiyO2 electrodes for rechargeable lithium cells 1993(12)
Keshiwagi H.nishi N Ichikawa T, et al. Charge - discharge characteristics for mesophase- pitch-based carbon fibers for lithium cells 1993(2)

引证文献(17条) 
吴雪平 锂离子电池生产过程中的重要质量管控点 [期刊论文] -电池2008(5)
唐致远.贺艳兵.刘元刚.刘强.阳晓霞 负极集流体铜箔对锂离子电池的影响 [期刊论文] -腐蚀科学与防护技术2007(04)
孟德龙.陈为亮.伍贺东.张凌义.黄中省 掺杂对正极材料LiNi0.8Co0.2O2电化学性能的影响 [期刊论文] -云南冶金2007(03)
蓝海江.丁红 非正常使用对锂离子电池的影响 [期刊论文] -柳州师专学报2007(01)
雷娟.蒋新华.解晶莹 锂离子电池组的内阻在线检测系统的设计 [期刊论文] -电池2007(02)
周姣红.李奇.叶伟.熊英.曾曦 LiNi0.8Co0.2O2正极的电性能 [期刊论文] -有色金属2006(02)
周姣红 锂离子电池复合正极的性能研究 [学位论文] 硕士2006
周姣红 锂离子电池复合正极的性能研究 [学位论文] 硕士2006
马国胜.高虹.杨国生.王通洲 锂离子电池正极材料LiMn2O4的LiCoO2包覆性能研究 [期刊论文] -辽宁化工2005(07)
刘伯文.耿海龙.王新东.王建武.吴国良.卢世刚 粘结剂对锂离子蓄电池性能的影响 [期刊论文] -电源技术2005(05)

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