从热力学、动力学及乙醇渗透等方面,综述了直接乙醇燃料电池(DEFC)研究面临的挑战.从热力学角度看,在低温(<100℃)时,乙醇的最大热力学转化效率低于14%,降低了DEFC的效率;从动力学角度看,目前对乙醇氧化活性最高的Pt-Sn催化剂仍不能使乙醇完全氧化,降低了DEFC的法拉第效率;乙醇渗透可能带来的后果,加大了研究的困难性.
作 者:宋树芹 王毅 沈培康 SONG Shu-qin WANG Yi SHEN Pei-kang
作者单位:中山大学光电材料与技术国家重点实验室,广东,广州,510275
刊 名:电池 ISTIC PKU
英文刊名:BATTERY BIMONTHLY
年,卷(期):2007 37(6)
分类号:TM911.46
关键词:直接乙醇燃料电池(DEFC) 乙醇氧化 乙醇渗透
机标分类号:O64 TM9
机标关键词:直接乙醇燃料电池热力学乙醇渗透法拉第效率动力学转化效率氧化活性完全氧化困难性催化剂综述
基金项目:
DOI:
参考文献(24条)
1.James L.Andrew D Fuel Cell Systems Explained 2003
2.衣宝廉 燃料电池--原理@技术@应用 2003
3.俞耀伦.孙公权.辛勤 阳极催化层孔结构对DMFC性能的影响 [期刊论文] -电池2007(1)
4.梁剑莹.李永亮.沈培康 PEMFC关键组件的研究进展 [期刊论文] -电池2006(3)
5.赵培.木士春.潘牧.袁润章 PEMFC组件CCM制备方法的评述 [期刊论文] -电池2005(6)
6.Heinzel A.Barragán V M A review of the state-of-the-art of the methanol crossover in direct methanol fuel cells 1999(1)
7.宋树芹.陈利康.刘建国.魏昭彬.辛勤 直接乙醇燃料电池初探 [期刊论文] -电化学2002(1)
8.Zhao X S.Li W Z.Jiang L H Multi-wall carbon nanotube supported Pt-Sn nanoparticles as an anode catalyst for the direct ethanol fuel cell 2004(15)
9.Zhou W J.Li W Z.Song S Q Bi-and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells 2004(1-2)
10.Song S Q.Zhou W J.Liang Z X The effect of methanol and ethanol cross-over on the performance of PtRu/C-based anode DAFCs 2005(1)
11.宋树芹 直接乙醇燃料电池:乙醇渗透和MEA制备及其对DEFC单池性能的影响 [学位论文] 2004
12.Tricoli V Proton and methanol transport in poly(perfluorosulfonate)membranes containing Cs+ and H+ cations 1998(11)
13.Song S Q.Zhou W J.Zhou Z H Direct ethanol PEM fuel cells:the case of platinum based anodes 2005(9)
14.Iwasita T.Pastor E A dems and FT ir spectroscopic investigation of adsorbed ethanol on polycrystalline platinum 1994(4)
15.Lamy C.Rousseau S.Belgsir E M Recent progress in the direct ethanol fuel cell:development of new platinum-tin electrocatalysts 2004(22-23)
16.Zhou W J.Song S Q.Li W Z Direct ethanol fuel cells based on PtSn anodes:the effect of Sn content on the fuel cell performance 2005(1)
17.宋树芹.梁振兴.周卫江.孙公权.辛勤 DMFC的阻甲醇渗透研究进展 [期刊论文] -电池2004(4)
18.Kim Y M.Park K W.Choi J H A Pd-impregnated nanocomposite Nafion membrane for use in high-concentration methanol fuel in DMFC 2003(7)
19.Finsterwalder F.Hambitzer G Proton conductive thin films prepared by plasma polymerization 2001(1)
20.Kreuer K D.Fuchs A.Ise M Imidazole and pyrazole-based proton conducting polymers and liquids 1998(10-11)
21.Wei Z B.Wang S L.Yi B L Influence of electrode structure on the performance of a direct methanol fuel cell 2002(1-2)
22.Calabrese B S.Patterson T.Wang E Mixed-reactant,strip-cell direct methanol fuel cells 2001(2)
23.Argyropoulos P.Scott K.Taama W M Dynamic response of the direct methanol fuel cell under variable load conditions 2000(1-2)
24.Boysen D A.Uda T.Chisholm C R I High-performance solid acid fuel cells through humidity stabilization 2004(5654)
