介绍了单斜晶型A-Li3V2(PO4)3和正交晶型B-Li3V2(PO4)3的结构和电化学性质;综述了Li3V2(PO4)3的制备方法(包括离子交换法、高温固相法、低温合成法、溶胶-凝胶法和微波法)及其优缺点;简述了LiaV2(PO4)3的充放电机理及改性研究的现状.
作 者:朱先军 刘云霞 耿良梅 程龙兵 ZHU Xian-jun LIU Yun-xia GENG Liang-mei CHEN Long-bing
作者单位:华中师范大学化学学院,湖北,武汉,430079
刊 名:电池 ISTIC PKU
英文刊名:BATTERY BIMONTHLY
年,卷(期):2007 37(5)
分类号:TM912.9
关键词:Li3V2(PO4)3 锂离子电池 合成方法
机标分类号:TM9 O64
机标关键词:锂离子电池正极材料离子交换法高温固相法低温合成法充放电机理制备方法晶型化学性质改性研究微波法凝胶法综述正交溶胶结构
基金项目:国家自然科学基金,湖北省自然科学基金
DOI: 参考文献(24条) 1.余章华.汪莉.周运鸿 混合动力汽车用锂离子电池的研究 [期刊论文] -电池2005(4)
2.Balakrishnan P G.Ramesh R.Prem T Safety mechanism in lithium ion battery 2006(2)
3.Padhi A K.Nanjundaswamy K S.Masquelier C Mapping of transition metal redox energies in phosphates with NASICON structure by lithium intercalation 1997(8)
4.Saidi M Y.Barker J.Huang H Performance characteristics of lithium vanadium phosphate as a cathode material for lithium ion batteries 2003
5.Barker J.Gover R K B.Burns P The effect of Al substitution on the electrochemical insertion properties of lithium vanadium phosphate,Li3V2(PO4)3 2007(4)
6.Yin S C.Gronodey H.Strobel P Electrochemical property:structure relationships in monodinic Li3-yV2(PO4)3 2003(34)
7.Ganbicher J.Wurm C.Goward G Rhombohedral form of Li3v2(PO4)3 as a cathode in Li-ion batteries 2000(11)
8.Morcrette M.Leriches J B.Patoux S In situ X-ray diffraction during lithium extraction from rhombohedral and monoclinic Li3V2 (PO4)3 2003(5)
9.唐志远.焦延峰 磷酸铁锂锂离子电池正极材料的研究 [期刊论文] -化工中间体2005(12)
10.Saidi M Y.Barker J.Huang H Electrochemical property of lithium vanadium phosphate as a cathode material for lithium ion batteries 2002(7)
11.Yin S C.Strobel P S.Grondey H Li2.5V2(PO4)3:a roomtemperature analogue to the fast-ion conducting high-temperature λphase of Li3V2(PO4)3 2004(8)
12.Barker J.Saidhi M Y.Swoyer J L Electrochemical properties of beta LiVOPO4 prepared by csrbothermal reduction 2004(6)
13.Barker J.Saidhi M Y.Swoyer J L Carbothermal reduction method for the preparation of electroactive materials for lithium ion applications 2003(6)
14.Fu P.Zhao Y M.Dong Y Z Synthesis of Li3V2(PO4)3 high performance by optimized solid-state synthesis routine 2006(1)
15.Fu P.Zhao Y M.Dong Y Z Low temperature solid-state synthesis routine and mechanism for Li3V2(PO4)3 using LiF as lithium precursor 2006(3)
16.刘素琴.唐联兴.黄可龙.李世彩 溶胶-凝胶法制备Li3V2(PO4)3及其性能研究 [期刊论文] -无机化学学报2006(6)
17.钟胜奎.尹周澜.王志兴.陈启元 低温固相反应合成Li3V2(PO4)3正极材料及其性能 [期刊论文] -无机化学学报2006(10)
18.Saitoh M.Yoshida S.Yamane H Capacity fading of the acid treated lithium manganese oxides in high temperature storage 2003(2)
19.任慢慢.李宇展.周震.高学平.阎杰 微波法合成正极材料Li3V2(PO4)3 [期刊论文] -电池2006(1)
20.Yin S C.Gronodey H.Strobel P Charge ordering in lithium vanadium phosphates:electrode materials for lithium-ion batteries 2003(34)
21.Cahill L S.Chapman R P.Britain J F 7Li NMR and twodimensional exchange study of lithium dynamics in monodinic Li3V2 (PO4)3 2006(14)
22.Atsuo Y.Mamoru H.Chung S C Olivine type cathodes achievements and problema 2003
23.Huang H.Yin S C.Kerr T Nanostructured composites:a high capacity,fast rate Li3Vz(PO4)/carbon cathode for rechargeable lithium batteries 2002(21)
24.Sato M.Ohkawa H.Yoshida K EnhanCement of discharge capacity of Li3V2(PO4)3 by stabilizing the orthorhombic phase at room temperature 2000(1-4)
引证文献(2条)
1.刘云霞.章芳琴.耿良梅.程龙兵.朱先军 Li3V2(PO4)3掺镍的性能研究 [期刊论文] -华中师范大学学报(自然科学版)2008(4)
2.郭孝东.钟本和.唐艳.廖文华.吴德桥 Mg2+掺杂对锂离子正极材料Li3V2(PO4)3的影响 [期刊论文] -化学研究与应用2008(05)
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