二巯基噻二唑(DMcT)作为锂离子电池正极材料,具有容量高、寿命长、制备简便等优点,但它在室温下的反应速度较慢.介绍DMcT在锂离子电池中的充放电机理及利用聚苯胺、聚吡咯、聚3,4-乙撑二氧噻吩、聚邻甲基苯胺、聚N-甲基化苯胺、聚3-烷基酯-4-甲基吡咯、聚3-丁基酯-4-甲基吡咯、聚二巯基噻二唑、金属离子以及金属纳米粉等电催化剂对DMcT进行改性的研究进展,以及电催化剂对DMcT电化学性能的影响.通过这些改性,DMcT的放电容量、正极电流、循环寿命都得到了改善.
作 者： 张敬华 舒东 张永生 孟跃中 ZHANG Jing-hua SHU Dong ZHANG Yong-sheng MENG Yue-zhong  
作者单位： 张敬华,ZHANG Jing-hua(中山大学能源与环境材料研究所,广东,广州,510275;中国地质科学院矿产资源研究所,北京,100037)
舒东,孟跃中,SHU Dong,MENG Yue-zhong(中山大学能源与环境材料研究所,广东,广州,510275)
张永生,ZHANG Yong-sheng(中国地质科学院矿产资源研究所,北京,100037) 
刊 名： 电池  ISTIC PKU
英文刊名： BATTERY BIMONTHLY 
年，卷(期)： 2005 35(3) 
分类号： TM912.9 
关键词： 锂离子电池   正极材料   二巯基噻二唑   电催化剂  
机标分类号： TM9 O64 
机标关键词： 锂离子电池正极材料二巯基噻二唑聚邻甲基苯胺电催化剂乙撑二氧噻吩聚吡咯金属纳米粉电化学性能充放电机理循环寿命放电容量金属离子改性反应速度寿命长室温下聚苯胺甲基化烷基丁基 
基金项目： 教育部留学回国人员科研启动基金，中国博士后科学基金 
DOI：  

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引证文献(3条) 
刘玉婷.晏会新.尹大伟.吕博 2,5-二取代-1,3,4-噻二唑类化合物的合成及应用研究 [期刊论文] -精细化工中间体2009(1)
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唐致远.高飞.韩彬 锂离子电池负极材料Li4Ti5O12的研究进展 [期刊论文] -化工进展2006(02)

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