介绍了LiCoO2、LiNiO2、LiMn2O4及LiFePO4等纳米正极材料的合成方法及性能;提出了纳米正极材料应用中存在的问题,如Li+脱出困难、SEI膜消耗的Li+增多及制备参数要求苛刻等.
作 者: 林晓园 陈立宝 唐开枚 王太宏
作者单位: 湖南大学物理与微电子科学学院,湖南,长沙,410082
刊 名: 电池 ISTIC PKU
英文刊名: BATTERY BIMONTHLY
年,卷(期): 2009 39(4)
分类号: TM912.9
关键词: 锂离子电池 纳米正极 合成
机标分类号: TM9 X16
机标关键词: 锂离子电池纳米正极材料问题materials for合成方法参数要求材料应用LiMn2O4LiFePO4LiCoO2SEI膜制备性能消耗脱出困难
基金项目:
DOI:
参考文献(24条)
Chen H L,Grey C P.Molten salt synthesis and high rate performance of the"desert-rose"form of LiCoO2[J].Adv Mater(Weinheim,Ger),2008,20(11):2 206-2 210.
Kim B H,Kim J H,Kwon I H,et al.Electrochemical properties of LiNiO2 cathode material synthesized by the emulsion method[J].Ceram 1nt,2007,33(5):837-841.
Tang S B,Lai M O,Lu L.Properties of nano-erystalline LiMn2O4 thin films deposited by pulsed laser deposition[J].Electrochim Acta,2006,52(3):1 161-1 168.
Caballero A,Cruz-Yusta M,Morales J,et al.A new and fast synthesis of nanosized LIFePO4 electrode materials[J].Eur J Inorg Chem,2006,2006(9):1 758-1 764.
Lee T,Cho K,Oh J,et al.Electrochemical characteristics of LiCoO2 nano-powder synthesized via aerosol flame deposition (AFD)[J].J Phys Chem Solids,2008,69(5 -6):1 242-1 245.
Predoana L,Barau A,Zaharescu M,et al.Electrochemical properties of the LiCoO2 powder obtained by sol-gel method[J].J Eur Ceram Soc,2007,27(2-3):1 137-1 142.
Huang J J,Yang J J,Li W R,et al.Electrochemical properties of LiCoO2 thin film electrode prepared by ink-jet printing technique[J].Thin Solid Films,2008,516(10):3 314-3 319.
LI Kai-hui(李凯慧),ZHANG Shao-wen(张少文).LiNiO2的制备及其在充放电过程中的结构变化[J].Journel of Zhengzhou University of Light Industry(Natural Science Edition)[郑州轻工业学院学报(自然科学版)],2006,21(2):26-28.
Kim C J,Ahn I S,Cho K K,et al.Characteristics of LiNiO2 thin films synthesized by Li diffusion on the surface oxidized epitaxiel layer of Ni-alloy[J].J Alloys Compd,2008,449(1-2):335-338.
Subramania A,Angayarkanni N,Vasudevan T.Effect of PVA with various combustion fuels in sol-gel thermolysis process for the synthesis of LiMn2O4 nanoparticles for Li-ion batteries[J].Mater Chem Phys,2007,102(1):19-23.
Raja M W,Mabanty S,Ghosh P,et al.Alanine-assisted low-temperature combustion synthesis of nanocrystalline LiMn2O4 for lithiumion batteries[J].Mater Res Bull,2007,42(8):1 499-1 506.
HU Wei-guo(胡卫国),HUANG Ke-long(黄可龙),SHEN Guo-pei(申国培),et al.LiMn2O4的甘氨酸法合成[J].Battery Bimonthly(电池),2008,38(1):8-10.
Wu H M,Tu J P,Yuan Y F,et al.One-step synthesis LiMn2O4 cathode by a hydrothermal method[J].J Power Sources,2006,161(2):1 260-1 263.
Jiang C H,Dou S X,Liu H K,et al.Synthesis of spinel LiMn2O4 nanoparticles through one-step hydrothermal reaction[J].J Power Sources,2007,172(1):410-415.
Cabana J,Valdes-Solfs T,Palacun M R,et al.Enhanced high rate performance of LiMn2O4 spinel nanoperticles synthesized by a hard-tempiate route[J].J Power Sources,2007,166(2):492-498.
WU Jian-bo(吴建波),HUANG Ke-long(黄可龙),LIU Su-qin(刘素琴).尖晶石型LiMn2O4薄膜电极的制备及电化学性质[J].Battery Bimonthly(电池),2006,36(3):181-183.
Panero S,Scrosati B,Wachtler M,et al.Nanotechnology for the progress of lithium batteries R&D[J].J Power Sources,2004,129(1):90-95.
WANG Zhi-gao(王志高),LI Jian-ling(建玲),WANG Xin-dong(王新东).LiFePO4/C的微波法制备和性能[J].Battery Bimonthly(电池),2006,36(2):142-143.
Wang L N,Zhan X C,Zhang Z G,et al.A soft chemistry synthesis routine for LiFePO4-C using a novel carbon source[J].J Alloys Compd,2008,456(1-2):461-465.
ZHU Bing-quan(朱炳权),LI Xin-hai(李新海),ZHANG Bao(张宝),et al.改进的碳热还原法制备正极材料LiFePO4/C[J].Battery Bimonthly(电池),2005,35(6):445-447.
Jin E M,Jin B,Jun D K et al.A study on the electrochemical characteristics of LiFePO4 cathode for lithium polymer batteries by hydrothermal method[J].J Power Sources,2008,178(2):801-806.
Lee S B,Cho S H,Cho S J et al.Synthesis of LiFePO4 material with improved cycling performance under harsh conditions[J].Electrechem Commun,2008,10(9):1 219-1 221.
Gao F,Tang Z Y,Xue J J.Preparation and characterization of nano-partiele LiFePO4 and LiFePO4/C by spray-drying and postannealing method[J].Electrochim Acta,2007,53 (4):1 939-1 944.
LIU Hong-tao(刘洪涛),GE Shi-rong(葛世荣).纳米颗粒团聚双峰分布机制研究[J].Lubrication Engineering(润滑与密封),2007,32(12):1-8.
